A ferrocene-based pseudopeptide chiroptical switch (CROSBI ID 291632)
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Podaci o odgovornosti
Opačak, Saša ; Babić, Darko ; Perić, Berislav ; Marinić, Željko ; Smrečki, Vilko ; Pem, Barbara ; Vinković Vrček, Ivana ; Kirin, Srećko I.
engleski
A ferrocene-based pseudopeptide chiroptical switch
We present a double-stranded ferrocene pseudopeptide 2b which exhibits stimuli responsive chirality inversion triggered by solvent exchange or acid addition. Compound 2b exists as a mixture of self-assembled fast exchanging oligomers which macroscopically behave as a chiroptical switch with two stable states. The ferrocene group inversion results in a distinct CD signal in the visible part of the spectra. The inversion is accomplished through a conformational change due to a rearrangement of hydrogen bonding forcing the rotation of ferrocene rings.
chiroptical switch ; ferrocene ; circular dichroism ; aggregation ; chirality inversion
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