engleski

A simulation of an initial stage of a pseudopolarographic experiment on a thin mercury film covered rotating disk electrode

A general theory of pseudopolarography using the thin film covered rotating disk electrode is developed. Half-wave potentials of pseudopolarograms of the reversible and totally irreversible redox reaction are given. Under the influence of the development of the diffusion layer in the first phase of the accumulation period, the limiting values of dimensionless pseudopolarograms incerase with decreasing accumulation time. The consequences of this process on the half-wave potentials are discussed.

pseudopolarography; mercury film covered electrode; rotating disk electrode; thin mercury film

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