Synthesis and X-ray single crystal structure analysis of an inorganic nucleoside analog (CROSBI ID 136707)
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Kirin, Srećko I. ; Ohr, Kristi ; Yennawar, Hemant P. ; Morgan, Christopher M. ; Levine, Lauren A. ; Williams, Mary Elizabeth
engleski
Synthesis and X-ray single crystal structure analysis of an inorganic nucleoside analog
The inorganic nucleoside analog [Boc-aeg{; ; Cu(pda)py-Ac}; ; -OMe] (3) is prepared and fully characterized. The X-ray single crystal analysis reveals that 3 assembles by apical Cu– O bonds into a coordination polymer, with short Cu– Cu distances of 5.32 and 5.78 Å ; . The solid state structure of 3 is in accordance with an isotactic structural model for charge neutral inorganic nucleic acids analogs. Aeg = (2-aminoethyl)glycine, py-Ac = 4-acetyl pyridine, pda = pyridine-2, 6-dicarboxylic acid.
artificial peptide; bioinorganic chemistry; coordination polymer; Cu(II) complex; nucleic acid analog; X-ray
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