Nitrosobenzene Cross-dimerization: Structural Selectivity in Solution and in Solid State (CROSBI ID 164191)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Biljan, Ivana ; Cvjetojević, Gorana ; Smrečki, Vilko ; Novak, Predrag ; Mali, Gregor ; Plavec, Janez ; Babić, Darko ; Mihalić, Zlatko ; Vančik, Hrvoj
engleski
Nitrosobenzene Cross-dimerization: Structural Selectivity in Solution and in Solid State
Possibility of nitrosobenzenes to form dimeric molecular structures (azodioxides) is used as a model for intermolecular selectivity investigations in solution as well as in solid state. Cross-dimerization of different combinations of p- and m-substituted nitrosobenzene pairs was studied by variable temperature 1H NMR, solid-state NMR (CP MAS), IR, and ab initio calculations. It is evident that p-nitronitrosobenzene behaves nonselectively because it forms dimers with all the studied nitrosobenzene partners. In contrast, p-methoxynitrosobenzene in most cases does not form dimers. The evidence that ability to form dimers is different in solution than in the solid state can be explained by influence of molecular arrangements in the crystal lattice.
nitrosobenzenes ; azodioxides ; cross-dimerization ; selectivity
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Podaci o izdanju
979 (1-3)
2010.
22-26
objavljeno
0022-2860
10.1016/j.molstruc.2010.05.034