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Modeling of stability constants of mono-complexes of La3+, Ce3+, Pr3+, and Nd3+ with carboxylic acids in water–dioxane solutions by using connectivity index 3χv (CROSBI ID 188709)

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Miličević, Ante ; Raos, Nenad Modeling of stability constants of mono-complexes of La3+, Ce3+, Pr3+, and Nd3+ with carboxylic acids in water–dioxane solutions by using connectivity index 3χv // Chemical physics letters, 528 (2012), 63-67. doi: 10.1016/j.cplett.2012.01.023

Podaci o odgovornosti

Miličević, Ante ; Raos, Nenad

engleski

Modeling of stability constants of mono-complexes of La3+, Ce3+, Pr3+, and Nd3+ with carboxylic acids in water–dioxane solutions by using connectivity index 3χv

We developed two models for the estimation of stability constants in dioxane–water mixtures of monocomplexes of lanthanides (La3+, Ce3+, Pr3+, and Nd3+) with carboxylic acids (ethanoic, propanoic, and butanoic). The first, linear model proved suitable for the prediction of logK1 at low mass fractions of dioxane, w = 0–20% (r = 0.981, S.E. = 0.06), whereas the second, quadratic model, yielded better results at higher fractions, w = 40–60% (r = 0.980, S.E. = 0.10).

lanthanides; prediction of stability constants; acetate complexes; mixed solutions; topological indices

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Podaci o izdanju

528

2012.

63-67

objavljeno

0009-2614

10.1016/j.cplett.2012.01.023

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