Inorganic Spherical Cells: Versatile Platforms for New Phenomena at the Nanoscale (CROSBI ID 613424)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa
Podaci o odgovornosti
Garai, Somenath ; El Moll, Hani ; Rubčić, Mirta ; Merca, Alice ; Bögge, Hartmut ; Müller, Achim
engleski
Inorganic Spherical Cells: Versatile Platforms for New Phenomena at the Nanoscale
The unique spherical nanocapsules/Keplerates of the type {; ; ; ; ; {; ; ; ; ; (Mo)Mo5}; ; ; ; ; 12M’30 (M’ = {; ; ; ; ; MoV2}; ; ; ; ; , VIV, CrIII, FeIII) (more generally: (pentagon)12(spacer/ligand)30) allow – due to their exceptional structural features and easy variations/derivatizations – versatile chemistry and applications as well as the option to study new phenomena of interdisciplinary interest. In this poster we specially refer on the interesting neutral/charged species of [{; ; ; ; ; (MoVI)MoVI 5O21(L)6}; ; ; ; ; 12{; ; ; ; ; FeIII(H2O)L}; ; ; ; ; 30] (L = H2O/CH3COO- /Mo2O8/9 n-) 1a/type not only because of their tremendous unusual magnetic properties which exhibit spherical networks based on corner- shared M’3 triangles causing geometrical frustration analogous to that of the planar Kagomé lattices but also for their behavior as unique weak polyprotic acids owing to the external water ligands attached to the M’ metal centers. In the second part we refer to the fact that the capsule [{; ; ; ; ; (MoVI)MoVI 5O21(H2O)6}; ; ; ; ; 12{; ; ; ; ; MoV 2O4(CO3)}; ; ; ; ; 30]72- 2a containing 30 carbonate ligands is a potential starting reagent for the synthesis of novel capsules with weakly coordination ligands such as fluoride ions [{; ; ; ; ; (MoVI)MoVI5O21(H2O)5F}; ; ; ; ; 12 {; ; ; ; ; MoV2O4(F)(H2O)}; ; ; ; ; 30]69- 3a.
Polyoxometalates ; Keplerates
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
Podaci o prilogu
P11-P11.
2014.
objavljeno
Podaci o matičnoj publikaciji
3rd FMOCS – PoCheMoN Frontiers in Metal-Oxide Cluster Science Symposium & European conference “Polyoxometalate Chemistry for Molecular Nanoscience”
Proust, Anna ; Izzet, Guillaume ; Villanneau, Richard ; Dolbecq, Anne ; Lacôte, Emmanuel
Pariz:
Podaci o skupu
3rd FMOCS – PoCheMoN Frontiers in Metal-Oxide Cluster Science Symposium & European conference “Polyoxometalate Chemistry for Molecular Nanoscience”
poster
12.07.2014-15.07.2014
Maffliers, Francuska