Cyclopalladation of 4, 4’-disubstituted azobenzenes by palladium(II) acetate (CROSBI ID 649955)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija
Podaci o odgovornosti
Barišić, Dajana ; Budimir, Ana ; Juribašić Kulcsar, Marina ; Plavec, Janez ; Ćurić, Manda
engleski
Cyclopalladation of 4, 4’-disubstituted azobenzenes by palladium(II) acetate
Transition-metal mediated activation of a carbon−hydrogen bond is a common method for synthesis of cyclometallated compounds. Cyclopalladated compounds have been vastly investigated due to their unique chemical and physical properties that, when fully explored, enable them for application ranging from catalysts and active units in sensors to cancer treatment agents. Our group focuses on cyclopalladated azobenzenes that show promising photophysical properties in solution and in solid state. Here we report an NMR spectroscopic study of cyclopalladation of 4, 4′-disubstituted azobenzenes L1-L3 (Scheme 1) by palladium(II) acetate in DMF-d7. 1H monitoring of the reaction enabled an insight into the reaction progress and allowed identification of mono- and dicyclopalladated acetate products (major isomers are shown in Scheme 1).
NMR, palladation, azobenzene, acetate
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Podaci o prilogu
36-36.
2017.
objavljeno
Podaci o matičnoj publikaciji
Adriatic NMR Conference : Book of Abstracts
Namjesnik, Danijel ; Pičuljan, Katarina ; Bregović, Nikola ; Novak, Predrag
Zagreb: Prirodoslovno-matematički fakultet Sveučilišta u Zagrebu
978-953-6076-41-3
Podaci o skupu
Adriatic NMR Conference
poster
16.06.2017-18.06.2017
Mali Ston, Hrvatska