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NMR, CHEMOMETRIC AND GCxGC STUDIES OF CRUDE OILS, VACUUM RESIDUES AND VACUUM GAS OIL (CROSBI ID 652547)

Prilog sa skupa u zborniku | sažetak izlaganja sa skupa

Parlov Vuković, Jelena ; Hrenar, Tomica ; Plavec, Janez ; Friedrich, Miha ; Štajduhar, Luka ; Telen, Sanda ; Marinić Pajc, Ljiljana ; Novak, Predrag NMR, CHEMOMETRIC AND GCxGC STUDIES OF CRUDE OILS, VACUUM RESIDUES AND VACUUM GAS OIL. 2015

Podaci o odgovornosti

Parlov Vuković, Jelena ; Hrenar, Tomica ; Plavec, Janez ; Friedrich, Miha ; Štajduhar, Luka ; Telen, Sanda ; Marinić Pajc, Ljiljana ; Novak, Predrag

engleski

NMR, CHEMOMETRIC AND GCxGC STUDIES OF CRUDE OILS, VACUUM RESIDUES AND VACUUM GAS OIL

NMR spectroscopy in combination with statistical methods was used to study vacuum residues and vacuum gas oils from 32 crude oils of different origin. Two chemometric metodes were applied. Firstly, principal component analysis on complete spectra was used to perform classification of samples and clear distinction between vacuum residues and vacuum light and heavy gas oils were obtained. To quantitatively predict the composition of asphaltenes, principal component regression models using areas of resonance signals spaned by 11 frequency bins of the 1 H NMR spectra were build. A comprehensive two dimensional gas chromatography (GCxGC) was applied to identify different classes of hydrocarbons present in a selected crude oil. Pseudo two-dimensional DOSY NMR experiments were then used to assess the composition and structural properties of asphaltenes in a selected crude oil and its vacuum residue on the basis of their different hydrodynamic behavior and translational diffusion coefficients. DOSY spectra showed the presence of several asphaltene aggregates differing in size and interactions they formed. It has been shown that NMR spectroscopy coupled with statistical methods and GCxGC is a valuable tool for the investigation of crude oil and asphaltene samples

crude oil, NMR, statistical methods

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Podaci o prilogu

2015.

objavljeno

Podaci o matičnoj publikaciji

Podaci o skupu

SMASH 2015

poster

20.09.2015-23.09.2015

Baveno, Italija

Povezanost rada

Rudarstvo, nafta i geološko inženjerstvo