Controlling Orthogonal Self-Assembly through Cis-Trans Isomerization of a Non-Covalent Palladium Complex Dimer (CROSBI ID 246271)
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Podaci o odgovornosti
Kokan, Zoran ; Kovačević, Borislav ; Štefanić, Zoran ; Tzvetkova, Pavleta ; Kirin, Srećko I.
engleski
Controlling Orthogonal Self-Assembly through Cis-Trans Isomerization of a Non-Covalent Palladium Complex Dimer
The trans-configured square-planar complex of dichloropalladium and chiral monodentate phosphine ligands forms self-complementary dimers through 16 hydrogen bonded amides and π- π stacking in chlorinated solvents. The self- assembly is controled by cis-trans isomerisation of the metal center, where trans- configuration governs the dimer formation.
dichloropalladium ; chiral ; self-assembly
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