Symmetrical and asymmetrical carbohydrazides: a solid-state and solution study (CROSBI ID 657877)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija
Podaci o odgovornosti
Rubčić, Mirta ; Pisk, Jana ; Cindrić, Marina ; Vrdoljak, Višnja
engleski
Symmetrical and asymmetrical carbohydrazides: a solid-state and solution study
Carbohydrazide, i.e. 1, 3-diaminourea, represents a versatile building block for the design of symmetrical and asymmetrical urea- based componds. [1] Introduction of specific groups into the structure allows one to fine- tune the desired properties of such systems. For example, pyridine functionalized carbohydrazides proved to be an effective anion receptors, with the ability to stabilize small anion-water clusters.[2] On the other hand, monosubstituted pyridine based derivatives showed to be exquisite ligands for the design of dynamic metal-organic frameworks with intriguing anion-switchable properties.[3] Within this investigation we explored the synthetic opportunities towards selected mono- and bis- substituted carbonohydrazides, both symmetrical and asymmetrical ones, derived from 2, 3- and 2, 4- dihydroxybenzaldehyde, pyridinecarbaldehyde and carbohydrazide.[4] Dihydroxybenzaldehydes in combination with carbohydrazide yielded preferably bissubstituted symmetrical products, whereas in the case of pyridine based aldehydes monosubstituted derivatives were also isolated. The latter were then utilized as starting materials for the synthesis of bissubstituted asymmetrical compounds. All isolated products were thoroughly investigated in the solid-state by means of infrared (IR) spectroscopy, thermal analysis, powder X-ray diffraction (PXRD) and when suitable via single-crystal X-ray diffraction (SCXRD). The results point out to interesting differences in conformation between the symmetrical and asymmetrical derivatives in the solid state. Finally, the obtained compounds were explored in solution by appropriate one- and two- dimensional NMR techniques
carbohydrazide ; symmetrical and asymmetrical ligands ; NMR
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Podaci o prilogu
37-37.
2017.
objavljeno
Podaci o matičnoj publikaciji
Adriatic NMR Conference 2017 : Book of abstracts
Namjesnik, Danijel ; Pičuljan, Katarina ; Bregović, Nikola ; Novak, Predrag
Zagreb:
978-953-6076-41-3
Podaci o skupu
Adriatic NMR conference 2017
poster
16.06.2017-18.06.2017
Mali Ston, Hrvatska