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Another Example of Eight-Coordinated Molybdenum(IV) in the Structure of Tetrakis(methyl-2-mercaptonicotinato-N, S, N', S', N'', S'', N''', S''')molybdenum(IV), [Mo(C_5H_3NSCOOCH_3)_4] (CROSBI ID 104741)

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Cindrić, Marina ; Strukan, Neven ; Kajfež, Tanja ; Kamenar, Boris Another Example of Eight-Coordinated Molybdenum(IV) in the Structure of Tetrakis(methyl-2-mercaptonicotinato-N, S, N', S', N'', S'', N''', S''')molybdenum(IV), [Mo(C_5H_3NSCOOCH_3)_4] // Structural chemistry, 13 (2002), 3/4; 361-363-x

Podaci o odgovornosti

Cindrić, Marina ; Strukan, Neven ; Kajfež, Tanja ; Kamenar, Boris

engleski

Another Example of Eight-Coordinated Molybdenum(IV) in the Structure of Tetrakis(methyl-2-mercaptonicotinato-N, S, N', S', N'', S'', N''', S''')molybdenum(IV), [Mo(C_5H_3NSCOOCH_3)_4]

Tetrakis(methyl-2-mercaptonicotinato-N, S, N', S', N'', S'', N''', S''')molybdenum(IV), has been obtained by reaction of [MoCl_2(acac)_2] (or MoCl_4• 2CH_3CN) and 2-mercaptonicotinic acid in methanol. Esterification of 2-mercaptonicotinic acid indicates the catalytic role of molybdenum. The complex molecule contain molybdenum dodecahedraly coordinated by four sulfur and four nitrogen atoms.

2-Mercaptonicotinic acid; Esterification; Molybdenum(IV); Crystal structure; Dodecahedron

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Podaci o izdanju

13 (3/4)

2002.

361-363-x

objavljeno

1040-0400

Povezanost rada

Kemija

Indeksiranost