Another Example of Eight-Coordinated Molybdenum(IV) in the Structure of Tetrakis(methyl-2-mercaptonicotinato-N, S, N', S', N'', S'', N''', S''')molybdenum(IV), [Mo(C_5H_3NSCOOCH_3)_4] (CROSBI ID 104741)
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Cindrić, Marina ; Strukan, Neven ; Kajfež, Tanja ; Kamenar, Boris
engleski
Another Example of Eight-Coordinated Molybdenum(IV) in the Structure of Tetrakis(methyl-2-mercaptonicotinato-N, S, N', S', N'', S'', N''', S''')molybdenum(IV), [Mo(C_5H_3NSCOOCH_3)_4]
Tetrakis(methyl-2-mercaptonicotinato-N, S, N', S', N'', S'', N''', S''')molybdenum(IV), has been obtained by reaction of [MoCl_2(acac)_2] (or MoCl_4• 2CH_3CN) and 2-mercaptonicotinic acid in methanol. Esterification of 2-mercaptonicotinic acid indicates the catalytic role of molybdenum. The complex molecule contain molybdenum dodecahedraly coordinated by four sulfur and four nitrogen atoms.
2-Mercaptonicotinic acid; Esterification; Molybdenum(IV); Crystal structure; Dodecahedron
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