engleski

Diels-Alder reactions of C-phenylalted siloles with 1, 4-epoxy-1, 4-dihydronaphthalene

Preparation of a novel type of cycloadducts composed of a 7-silanorbornene ring condensed to the 7-oxanorbornene moiety (5-7) is described and their spectroscopic features are discussed in detail. The X-ray data for 5 are also presented. Finally, formation of silanole 8 by nucleophilic cleavage of an endocyclic silicon-carbon bond in 7 is described.

7-silanorbornene; Diels-Alder reaction; high-pressure chemistry; stereochemistry; X-ray

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