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Deuterium labeling study of the gas-phase reaction of Fe^+/Cr^+ with Pyrene by FTMS

A ~ 10 :1 mixture of deuterated with undeuterated pyrene was used to study the product composition in the reaction with various ratios of Fe+ and Cr+ (10 :1 to 1: 10) ions in a Fourier-transform mass spectrometer. None of the products FePy+, CrPy+, Py+, FePy2+, CrPy2+ and Py2+ showed deviation from the statistically expected composition.

Deuterium labeling study

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