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A minimum separating diffusion and adsorption waves in polarography using a static mercury drop electrode (CROSBI ID 81676)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Lovrić, Milivoj A minimum separating diffusion and adsorption waves in polarography using a static mercury drop electrode // Journal of electroanalytical chemistry (1992), 465 (1999), 1; 30-36. doi: 10.1016/S0022-0728(99)00013-3

Podaci o odgovornosti

Lovrić, Milivoj

engleski

A minimum separating diffusion and adsorption waves in polarography using a static mercury drop electrode

A sampled dc polarogram of a reversible redox reaction complicated by the reactant adsorption on the surface of the static mercury drop electrode may consist of a main wave and a post-wave which are separated by a minimum. This phenomenon is analysed theoretically for Langmuir and Frumkin isotherms. The minimum is a part of the postwave. It appears in the potential range in which the maximum surface coverage is diminished below 0.8. The minimum is the consequence of the change of the current-time relationship during the life-time of a single drop. A minimum followed by a very steep postwave is an indication of strong lateral attractions in the adsorbed layer.

Diffusion; Adsorption; Polarography; Dropping mercury electrode

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Podaci o izdanju

465 (1)

1999.

30-36

objavljeno

1572-6657

10.1016/S0022-0728(99)00013-3

Povezanost rada

Kemija

Poveznice
Indeksiranost