engleski

Five-co-ordinate cobalt(II) and nickel(II) complexes of 1, 4, 8, 11-tetrakis(diphenylphosphinomethyl)-1, 4, 8, 11-tetraazacyclotetradecane (tpta), [MCl(tpta)]X [X = ClO_4, BF_4, PF_6 and B(C_6H_5)_4]. Crystal structures of [CoCl(tpta)]ClO_4×C_6H_6 and [NiCl(tpta)]ClO_4×C_6H_6

A series of five-co-ordinate cobalt(II) and nickel(II) complexes with 1, 4, 8, 11-tetrakis(diphenylphosphinomethyl)-1, 4, 8, 11-tetraazacyclotetradecane (tpta) has been prepared and characterized. The complexes are high-spin paramagnetic substances, 1:1 electrolytes, consistent with the general formula [MCl(tpta)]X [M = Co, Ni ; X = ClO_4, BF_4, PF_6 and B(C_6H_5)_4]. A binuclear cobalt(II) complex of the formula [(CoCl_2)_2(tpta)]×H_2O has also been isolated. The crystal and molecular structures of [CoCl(tpta)]ClO_4×C_6H_6 and [NiCl(tpta)]ClO_4×C_6H_6 have been determined. The complexes have a distorted square-pyramidal geometry around the metal which is co-ordinated by four nitrogen atoms from the tpta ligand and an apical chlorine atom bound on the side of the four pendant chains of the macrocyclic ring. The distortions are greater in the cobalt complexes and are of the trigonal-bipyramidal type.

five-co-ordinate complexes; cobalt(II) complexes; nickel(II) complexes; macrocyclic ligands; crystal structures

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