Molybdenum(V) and molybdenum(IV) complexes with trifluorothioacetylacetone. X-ray structure of [Mo_2O_3{;CF_3C(O)CHC(S)CH_3};_4] (CROSBI ID 82654)
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Podaci o odgovornosti
Cindrić, Marina ; Matković-Čalogović, Dubravka ; Vrdoljak, Višnja ; Kamenar, Boris
engleski
Molybdenum(V) and molybdenum(IV) complexes with trifluorothioacetylacetone. X-ray structure of [Mo_2O_3{;CF_3C(O)CHC(S)CH_3};_4]
The novel complexes [Mo_2O_3(Sfta)_4] (1) and [MoCl_2(Sfta)_2] (2) (where Sfta = 1, 1, 1-trifluorothioacetylacetonate) were prepared by the reactions of [Mo_2O_3(O_2CCH_3)_4] and MoCl_4 with 1, 1, 1-trifluorothioacetylacetone. The crystal structure of (1) has been determined from single crystal diffractometer data and refined to the final R value of 0.060. The complex (1) consists of dinuclear molecules bridged by an oxo-oxygen atom. Molybdenum atoms exhibit distorted octahedral coordinations
molybdenum; 1; 1; 1-trifluorothioacetylacetone; crystal structure
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Podaci o izdanju
1 (7)
1998.
237-238-x
objavljeno
1387-7003
10.1016/S1387-7003(98)00060-4