Electrochemical cleavage of S-N bond of anhydro-2-azacephams at mercury electrode (CROSBI ID 130966)
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Podaci o odgovornosti
Mandić, Zoran ; Tomšić, Slavica ; Bratoš, Igor
engleski
Electrochemical cleavage of S-N bond of anhydro-2-azacephams at mercury electrode
The electrochemical reduction of anhydro-2-azacephams at mercury electrode was studied. In all cases the S-N bond was cleaved. The products of the reaction consist of corresponding azetidine-2-sulfinate and azetidine-2-sulfonate anions. The electroreduction is complicated by the adsorption of reactants and products and it is very likely that an organo-mercury compound is formed as an intermediate in the process.
2-azacephams ; electroreduction ; cyclic voltammetry
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