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izvor podataka: crosbi

Molecular structure of bis[(1,3)2-oxaadamantano]-18-crown-6 and its potassium picrato complex (CROSBI ID 86638)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Mlinarić-Majerski, Kata ; Višnjevac, Aleksandar ; Kragol, Goran ; Kojić-Prodić, Biserka Molecular structure of bis[(1,3)2-oxaadamantano]-18-crown-6 and its potassium picrato complex // Journal of molecular structure, 554 (2000), 277-285-x

Podaci o odgovornosti

Mlinarić-Majerski, Kata ; Višnjevac, Aleksandar ; Kragol, Goran ; Kojić-Prodić, Biserka

engleski

Molecular structure of bis[(1,3)2-oxaadamantano]-18-crown-6 and its potassium picrato complex

The structure of bis[(1,3)2-oxaadamantano]-18-crown-6 (1) and its potassium picrato complex ([1-K](+)(C6H2N3O7)(-);) have been studied by means of NMR-spectroscopy, X-ray structure analysis and molecular mechanics calculations. In the gas phase and in the CDCl3 solution, in both 1 and [1-K](+) the most stable conformation of C-2h symmetry is found. However, in the solid state 1 adopts crystallographic C-i symmetry while its potassium picrato complex exhibits C-l symmetry.

Bis(2-oxaadamantano)-18-crown-6; Conformations; Molecular modelling; Crystal structure

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Podaci o izdanju

554

2000.

277-285-x

objavljeno

0022-2860

Povezanost rada

Kemija

Indeksiranost