Synthesis and Structure of [Mo_2O_4(acac)_2 thala]ˇ3C_2H_5OH with thala= 3-(2-thienyl)-DL-alanine as a third bridging ligand between two molybdenum atoms (CROSBI ID 89660)
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Cindrić, Marina ; Strukan, Neven ; Kajfež, Tanja. Giester, Gerald ; Kamenar, Boris ;
engleski
Synthesis and Structure of [Mo_2O_4(acac)_2 thala]ˇ3C_2H_5OH with thala= 3-(2-thienyl)-DL-alanine as a third bridging ligand between two molybdenum atoms
As part of our study on oxomolybdenum(V) complexes we present here synthesis and crystal structure of a novel dimeric oxomolybdate(V) [Mo_2O_4(acac)_2 thala]ˇ3C_2H_5OH (acac= acetylacetonato, thala= 3-(2-thienyl)-DL-alanine) in which two molybdenum atoms are being bridged not only by two oxo-oxygens but additionally by amino acid carboxylate group. Two octahedrally coordinated molybdenum atoms are singly bonded to each other at the distance of 2.5631(5) A.
molybdenum(V); 3-(2-thienyl)-DL-alanine; crystal structure
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