Determination of Electrostatic Contribution to Enthalpy of Charging at Metal Oxide/Electrolyte Interface (CROSBI ID 78773)
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Žalac, Suzana ; Kallay, Nikola
engleski
Determination of Electrostatic Contribution to Enthalpy of Charging at Metal Oxide/Electrolyte Interface
Interpretation of calorimetric measurements concerning the charging of metal oxide/aqueous electrolyte interface was developed. The interpretation is based on the surface complexation model and involves both 1-pK and 2-pK concept. The resulting relationships enable determination of standard reaction enthalpies of each assumed surface reaction, and also evaluation of the dependency of surface potential on pH.
metal oxides; charging; enthalpy
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