Synthesis of New Cyano-Substituted bis-Benzothiazolyl Arylfurans and Arylthiophenes (CROSBI ID 99328)
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Podaci o odgovornosti
Racane, Livio ; Tralić-Kulenović, Vesna ; Boykin, David W. ; Karminski-Zamola, Grace
engleski
Synthesis of New Cyano-Substituted bis-Benzothiazolyl Arylfurans and Arylthiophenes
The new compounds 2-[4-(6-Cyanobenzothiazol-2-yl)phenyl]-5-(6-cyanobenzothiazol-2-yl)fu-rane (6a) and 2-[4-(6-Cyanobenzothiazol-2-yl)phenyl]-5-(6-cyanobenzothiazol-2-yl)thiophene (6b) were synthesized by multistep reactions from the correspond 2-furan and 2-thiophene carboxaldehydes (way A), as well as from 2-furan and 2- thiophene carboxylic acids (way B). Route B involves one less step than route A, but the overall yields of the reaction are considerably lower.
bis-benzothiazole ; 6-cyanobenzothiazole ; furan ; thiophene
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