Amine and ether bis-1,2,3-triazole ligands and their transition metal complexes (CROSBI ID 715444)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa
Podaci o odgovornosti
Šajnović, Josipa ; Sačer, Leon ; Pantalon Juraj, Natalija ; Perić, Berislav ; Kirin, Srećko I. ; Raić- Malić, Silvana ; Jakopec, Silvio
engleski
Amine and ether bis-1,2,3-triazole ligands and their transition metal complexes
The stereochemistry of flexible tridentate ligands influences many important properties like stability and reactivity in a chemical or biological environment. Metal coordination with bis-1, 2, 3- triazole ligands is an unexplored area of research in comparison to the structurally related dipicolylamine derivatives. In this work, bis-1, 2, 3-triazole derivatives with unsubstituted N- and O-central donor atoms were prepared using click chemistry by the reaction of aromatic azides with dipropargylamine and dipropargyl ether, respectively. Coordination of transition metals was studied in solution by NMR and UV-Vis spectrometry, along with characterisation in solid-state by single- crystal X-ray crystallography. Our research has shown that these types of ligands prefer formation of ML2 metal complexes. Study of the stereochemical preferences is currently underway as these ligands are able to form cis-, trans-fac or mer-isomers.
1, 2, 3-triazole ; amine ; ether ; transition metal complex
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Podaci o prilogu
137-137.
2022.
objavljeno
Podaci o matičnoj publikaciji
XIV. susret mladih kemijskih inženjera : knjiga sažetaka = XIV Meeting of Young Chemical Engineers : Book of Abstracts
Žižek, Krunoslav ; Katančić, Zvonimir ; Kovačić, Marin
Zagreb: Hrvatsko društvo kemijskih inženjera i tehnologa (HDKI)
2718-2177
Podaci o skupu
XIV. susret mladih kemijskih inženjera (SMLKI 2022)
poster
24.02.2022-25.02.2022
Zagreb, Hrvatska