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izvor podataka: crosbi

The mechanism and kinetics of the electrochemical cleavage of azo bond of 2-hydroxy-5-sulfophenyl-azo-benzoic acids (CROSBI ID 107002)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Mandić, Zoran ; Nigović, Biljana ; Šimunić, Branimir The mechanism and kinetics of the electrochemical cleavage of azo bond of 2-hydroxy-5-sulfophenyl-azo-benzoic acids // Electrochimica acta, 49 (2004), 4; 607-615. doi: 10.1016/j.electacta.2003.09.015

Podaci o odgovornosti

Mandić, Zoran ; Nigović, Biljana ; Šimunić, Branimir

engleski

The mechanism and kinetics of the electrochemical cleavage of azo bond of 2-hydroxy-5-sulfophenyl-azo-benzoic acids

The electrochemical reduction of 2-hydroxy-5-[(4-sulfophenyl)azo]benzoic acid, 2-hydroxy-5-[(3-sulfophenyl)azo]benzoic acid, 2-hydroxy-5-[(2-sulfophenyl)azo]benzoic acid and 2-hydroxy-5-azo-benzoic acid has been carried out in aqueous solutions at glassy carbon electrode using cyclic voltammetry and chronoamperometry. The position of sulfo substituent relative to azo bridge as well as pH of the solution have significant impact on the electrochemical behavior of these compounds. It has been proposed that these compounds are reduced predominantly as hydrazone tautomers resulting in corresponding hydrazo compounds. The overall electrochemical reduction follows DISP2 mechanism, ultimately leading to the 5-amino salicylic acid and sulfanilic acid. The rate determining step is the homogenous redox reaction between intermediate hydrazo compound and 5-amino salicylic acid quinoneimine. The mechanism is proposed in which activated complex of 5-amino salicylic acid quinoneimine and intermediate hydrazo compound is formed with the simultaneous loss of one proton.

2-hydroxy-5-sulfophenyl-azo-benzoic acids ; cathodic reduction ; cyclic voltammetry ; chronoamperometry ; ECE reaction scheme

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Podaci o izdanju

49 (4)

2004.

607-615

objavljeno

0013-4686

1873-3859

10.1016/j.electacta.2003.09.015

Povezanost rada

Kemijsko inženjerstvo

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