The synthesis and properties of cyclotetradeca-1, 8-diene with adamantane as a building block (CROSBI ID 463271)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija
Podaci o odgovornosti
Mlinarić-Majerski, Kata ; Pavlović, Dražen ; Milinković, Vjekoslav ; Kojić-Prodić, Biserka
engleski
The synthesis and properties of cyclotetradeca-1, 8-diene with adamantane as a building block
The rapidly expanding field of supramolecular chemistry has revealed a number of useful building blocks for the synthesis of artificial receptor molecules. Continuing the studies of adamantane containing macrocyclic molecules, 4, 6:11, 13-di(1, 3-adamantano)cyclotetradeca-trans, trans-1, 8-diene (1) has been prepared. The structure of 1 was established by spectral and X-ray crystallographic methods. Dynamic NMR studies indicate that 1 is conformationally mobile. Using the coalescence temperature method, the transition state Gibbs energy of equilibrium process between two conformers was estimated to be ca.14.2 kcal/mol.
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Podaci o prilogu
42-42-x.
1996.
objavljeno
Podaci o matičnoj publikaciji
National Meeting of the American Chemical Society
Hall, S.S.
Washington (MD): American Chemical Society (ACS)
Podaci o skupu
National Meeting of the American Chemical Society
poster
24.03.1996-28.03.1996
New Orleans (LA), Sjedinjene Američke Države