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Speciation of Cr(III) and Cr(VI) by Ion-Exchange TLC (CROSBI ID 505920)

Prilog sa skupa u zborniku | sažetak izlaganja sa skupa

Bokić, Ljerka ; Petrović, Mira ; Horvat, Alka J.M. ; Vinko, S. Speciation of Cr(III) and Cr(VI) by Ion-Exchange TLC // New Achievements in Chromatography / Šegudović, Nikola (ur.). Zagreb: Hrvatsko društvo kemijskih inženjera i tehnologa (HDKI) ; Hrvatsko kemijsko drustvo, 1992. str. TLC-5-x

Podaci o odgovornosti

Bokić, Ljerka ; Petrović, Mira ; Horvat, Alka J.M. ; Vinko, S.

engleski

Speciation of Cr(III) and Cr(VI) by Ion-Exchange TLC

Continous use of chromium salts in a great number of industries has caused its dispersion in aquatic and soil environment. Chromium is commonly found in polluted soil and water in two oxidation states (III and VI). Analysis of these samples often requires speciation of Cr in order to distinguish between the toxic hexavalent form and the less toxic tervalent one. There are only few analytical methods for the simultaneous determination of Cr(III) and Cr(VI) in complex matrix (e.g. polarography). In the work presented a TLC method with speciation capabillity for chromium has been studied. Improvment in the selectivity of TLC was achieved by changing the chromatographic properties of the support by phisical modification. This method, involving solid cation exchanger Amberlite IRP-69 mixed with microcrystaline cellulose has been successfully utilized for the separation of Cr(III) and Cr(VI). A number of solvent systems (solutions of HCl, HNO3, H3PO4 and H2SO4, respectively in concentrations from 0.5 to 3.0 mol/L) and reagents for visualization (H2O2, 1, 5-diphenylcarbazide, alizarine S, dimethyl-glyoxime, 8-hydroxyquinoline) have been tested.

Cr speciation; Ion-exchange TLC

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Podaci o prilogu

TLC-5-x.

1992.

objavljeno

Podaci o matičnoj publikaciji

New Achievements in Chromatography

Šegudović, Nikola

Zagreb: Hrvatsko društvo kemijskih inženjera i tehnologa (HDKI) ; Hrvatsko kemijsko drustvo

Podaci o skupu

New Achievements in Chromatography

poster

13.10.1992-15.10.1992

Opatija, Hrvatska

Povezanost rada

Kemija