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Catechin antioxidant action at various pH studied by cyclic voltammetry and PM3 semi-empirical calculations (CROSBI ID 113424)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Martinez, Sanja ; Valek, Lidija ; Petrović, Željka ; Metikoš-Huković, Mirjana ; Piljac, Jasenka Catechin antioxidant action at various pH studied by cyclic voltammetry and PM3 semi-empirical calculations // Journal of electroanalytical chemistry (1992), 584 (2005), 2; 92-99. doi: 10.1016/j.jelechem.2005.07.015

Podaci o odgovornosti

Martinez, Sanja ; Valek, Lidija ; Petrović, Željka ; Metikoš-Huković, Mirjana ; Piljac, Jasenka

engleski

Catechin antioxidant action at various pH studied by cyclic voltammetry and PM3 semi-empirical calculations

The mechanism of catechin electro-oxidation at various pH was studied using cyclic voltammetry (C. V.) on the glassy carbon (G. C.) electrode and PM3 semi empirical calculations. The influence of activation of the surface of the G.C. electrode on C.V. results has been discussed. Mixed adsorption- diffusion control has been observed by applying mechanistic criteria of C. V. to the results obtained at the activated electrode. The calculated catechin diffusion coefficient D = 2.78 x 10-6 cm2 s-1. A linear increase of the current peak has been observed with the increase of substrate concentration up to 40 mikromol dm^-3 (surface coverage 10-11 mol cm^-2). In the whole investigated pH range, the dE/dpH value is very close to the anticipated Nernstian dependence of - 59 mV per pH indicating that the slope is not affected by the different sequences of e- and H+ transfer. Molecular modeling results show a decrease of 5 kcal mol-1 in deltaHoF (between radical and parent molecule) and a decrease of 6 eV in IP (of the parent molecule) when the parent molecule is changed from neutral to monoanionic form of catechin showing that both processes – hydrogen and electron abstraction are facilitated by deprotonation. Upon the increase in pH the mechanistic pathway of catechin oxidation changes from phenol/cation radical/phenoxyl radical to phenol/phenolate monoanion/phenoxyl radical. In the reaction with a free radical this is equivalent to the change from hydrogen to electron donation.

catechin ; oxidation ; cyclic voltammetry ; molecular modeling

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nije evidentirano

nije evidentirano

nije evidentirano

nije evidentirano

nije evidentirano

Podaci o izdanju

584 (2)

2005.

92-99

objavljeno

1572-6657

1873-2569

10.1016/j.jelechem.2005.07.015

Povezanost rada

Kemija, Kemijsko inženjerstvo

Poveznice
Indeksiranost