engleski

Bis(adamantylamine-kN)bis(1-phenylbutane- 1, 3-dionato-k2O, O')nickel(II)

In the title complex, [Ni(C10H9O2)2(C10H17N)2], the Ni atom, which occupies a special position at an inversion centre, has an octahedral environment formed by four O atoms of two chelate benzoylacetonates [Ni-O 2.0409 (16) and 2.0187 (16) A° , and O-Ni-O 90.36 (6)° ] and two N atoms of the adamantylamine ligands [Ni-N = 2.176 (2) A°]. The amine H atoms of the adamantylamine ligands do not participate in any hydrogen bonds, due to their steric shielding and the lack of accessible acceptors.

nickel ; adduct ; benzoylacetone ; adamantylamine ; crystall structure

nije evidentirano