(ą)-6, 7-Dihydro-1, 6, 11-trimethyl-5H-dibenz(c, e)azepine (CROSBI ID 81975)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Mrvoš-Sermek, Draginja ; Lončar-Tomašković, Linda ; Hergold-Brundić, Antonija ; Mintas, Mladen ; Nagl, Ante
engleski
(ą)-6, 7-Dihydro-1, 6, 11-trimethyl-5H-dibenz(c, e)azepine
In the title compound, C17H19N, the central sevenmembered azepine ring adopts a twisted- boat conformation. The molecule exhibits a huge deviation from planarity by rotation of the two fused ortho-methyl-substituted phenyl rings around the central C12-C14 single bond. The dihedral angle between the planes of these two rings amounts to 56.05 (4)o, with a cisoid arrangement around the C12-C14 bond. Because of this non-planarity, the molecule is axially chiral.
Dihydrodibenzazepine derivatives ; twisted-boat conformation
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Podaci o izdanju
54
1998.
877-879
objavljeno
0108-2701
1600-5759
10.1107/S0108270198000936