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Photoelectron Spectroscopy of Some trans-2, 2'-Disubstituted Stilbenes (CROSBI ID 116529)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Mintas, Mladen ; Jakopčić, Krešimir ; Klasinc, Leo Photoelectron Spectroscopy of Some trans-2, 2'-Disubstituted Stilbenes // Croatica chemica acta, 56 (1983), 263-267-x

Podaci o odgovornosti

Mintas, Mladen ; Jakopčić, Krešimir ; Klasinc, Leo

engleski

Photoelectron Spectroscopy of Some trans-2, 2'-Disubstituted Stilbenes

The He I photoelectron (PE) spectra of stilbene (1), 2, 2'-di-chlorostilbene (2), 2-amino-2'-chlorostilbene (3), 2, 2'-diaminostilbene (4) and 2, 2'-dinitrostilbene (5), all in their trans configuration are recorded and discussed. The electronic structure of 1-5 can well be described on the bases of the composite molecule method and simple Hückel molecular orbital (HMO) calculations. Results indicate the importance of substituent effects causing characteristic shifts of low energy electronic band systems in the PE spectra.

He I photoelectron (PE) spectra; stilbene derivatives; composite molecule method; Hückel molecular orbital (HMO) calculations

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Podaci o izdanju

56

1983.

263-267-x

objavljeno

0011-1643

Povezanost rada

Kemija