One-dimensional self-assembly of bis(3-benzylpentane- 2, 4-dionato)copper(II) in the solid state, mediated by weak C-H...O hydrogen bonding (CROSBI ID 125544)
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Judaš, Nenad ; Kaitner, Branko
engleski
One-dimensional self-assembly of bis(3-benzylpentane- 2, 4-dionato)copper(II) in the solid state, mediated by weak C-H...O hydrogen bonding
In the title complex, [Cu(C12H13O2)2], the copper(II) ion lies on a crystallographic centre of symmetry and exhibits a square-planar coordination environment formed by four O atoms of two chelate betha-diketonate ligands. The nearest neighbours of the copper(II) ion in the apical direction are two pi-C atoms of betha-diketonate ligands, 3.263 (2) A away from the metal ion. Molecules in the crystal are stacked face-to-face and held together by weak C-H...O hydrogen bonding and pi..pi stacking interactions.
bis(3-benzylpentane-2 ; 4-dionato)copper(II)
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