engleski

A Supramolecular structure of bis(1, 3-diphenyl-1, 3-propanedionato-O, O)(1, 10-phenanthroline- N, N)cobalt(II) based on C-H..O, C-H..pi and pi..pi interactions

The compound bis(1, 3-diphenyl-1, 3-propanedionato-O, O) (1, 10-phenanthroline-N, N) cobalt(II) (Co(DBM)2(1, 10-phe)) was investigated as a potential host component for functional inclusion materials. The molecules of the complex in the crystal (a=21.015(5) A, b=17.456(5) A, c=9.503(3) A, β =107.04(2), s.g. C 2/c) are centrosymmetric and assemble by way of C-H..O and C-H..pi hydrogen bonds as well as pi..pi stacking interactions to provide a supramolecular ladder-like motif that is accompanied by a variant of the six phenyl-embrace synthon.

bis(1; 3-diphenyl-1; 3-propanedionato-O; O’ )(1; 10-phenanthroline-N; N’ )cobalt(II)

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