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Mercury(II) halide complexes with 1, 3-imidazole-2-thione. Crystal structures of di-mi-iodo-bis(1, 3-imidazolium-2-thiolato-S)mercury(II)) and bis(bromo(1, 3-imidazolium-2-thiolato-S))mercury(II)

Mercury(II) complexes with heterocyclic molecules containing nitrogen and an exocyclic thione (thioketo) group can be used to imitate mercury-cysteine thionato interactions in biosystems.Structural characterization can give better understanding of the toxicological behaviour of mercury. As a continuation of our interest in such mercury complexes we describe here the complexes of mercury(II) iodide and bromide with 1, 3-imidazole-2-thione.

mercury(II); 1; 3-imidazole-2-thione; crystal structures; di-mi-iodo-bis(1; 3-imidazolium-2-thiolato-S)mercury(II)); bis(bromo(1; 3-imidazolium-2-thiolato-S))mercury(II)

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