Synthesis, crystal structure, spectroscopic and thermal properties of [Et4N][Ta6Br12(H2O)6]Br4·4H2O (Et=ethyl)—A new compound with the paramagnetic [Ta6Br12]3+ cluster core (CROSBI ID 146674)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Perić, Berislav ; Jozić, Dražan ; Planinić, Pavica ; Brničević, Nevenka ; Giester, Gerald
engleski
Synthesis, crystal structure, spectroscopic and thermal properties of [Et4N][Ta6Br12(H2O)6]Br4·4H2O (Et=ethyl)—A new compound with the paramagnetic [Ta6Br12]3+ cluster core
A new hexanuclear cluster compound, [Et4N][Ta6Br12(H2O)6]Br4·4H2O (Et=ethyl) (1), with the paramagnetic [Ta6Br12]3+ cluster entity, was synthesized and characterized by elemental and TG/DTA analyses, IR and UV/Vis spectroscopy and by a single-crystal X-ray diffraction study. The presence of the paramagnetic [Ta6Br12]3+ unit was confirmed also by the room-temperature magnetic and EPR measurements. The compound crystallizes in the tetragonal I41/a space group, with a=14.299(5), c=21.241(5) Å, Z=4, R1(F)/wR2(F2)=0.0296/0.0811. The structure contains discrete [Ta6Br12(H2O)6]3+ cations with an octahedron of metal atoms edge-bridged by bromine atoms and with water molecules occupying all six terminal positions. The cluster units are positioned in the vertices of the three-dimensional (pseudo)diamond lattice. The structure shows similarities with literature reported structures of cluster compounds crystallizing in the diamond (Fd3 ̅m) space group.
synthesis ; crystal structure ; IR and UV/Vis spectroscopy ; paramagnetic hexanuclear tantalum cluster ; [Ta_6Br_12]3+ cluster units
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
Podaci o izdanju
182 (9)
2009.
2443-2450
objavljeno
0022-4596
1095-726X
10.1016/j.jssc.2009.06.026