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New Polycyclic Furan Derivatives by Trapping of the Photochemical Intermediates (CROSBI ID 473228)

Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija

Škorić, Irena ; Basarić, Nikola ; Marinić, Željko ; Šindler-Kulyk, Marija New Polycyclic Furan Derivatives by Trapping of the Photochemical Intermediates // 8th Blue Danube Symposium on Heterocyclic Chemistry, BLED / Stanovnik, Branko ; Svete, Jurij (ur.). Ljubljana: -, 2000. str. 146-146-x

Podaci o odgovornosti

Škorić, Irena ; Basarić, Nikola ; Marinić, Željko ; Šindler-Kulyk, Marija

engleski

New Polycyclic Furan Derivatives by Trapping of the Photochemical Intermediates

In our previous papers on the photochemistry of heteroaromatic stilbene like compounds we demonstrated the first example of an intramolecular photocycloaddition in which a 2-furyl beta-substituted compounds (1) give the bicyclo[3.2.1]octadiene derivatives (2). The mechanism of the reaction that we proposed included the formation of the intermediates 3. By irradiation of the starting compound 1a and its benzo derivative 1b under proper conditions the intermediates 3a, b were detected and transformed to 4, 5, 6 and 7. All the compounds were isolated and characterised by 2 D NMR techniques.

photochemistry; cycloaddition; bicyclo[3.2.1]octadiene; furan; benzofuran

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Podaci o prilogu

146-146-x.

2000.

objavljeno

Podaci o matičnoj publikaciji

8th Blue Danube Symposium on Heterocyclic Chemistry, BLED

Stanovnik, Branko ; Svete, Jurij

Ljubljana: -

Podaci o skupu

8th Blue Danube Symposium on Heterocyclic Chemistry

poster

24.09.2000-27.09.2000

Bled, Slovenija

Povezanost rada

Kemija