Diiodobis(1-methyl-1, 3-imidazolium-2-thiolato-S)mercury(II) (CROSBI ID 86810)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Pavlović, Gordana ; Popović, Zora ; Soldin, Željka ; Matković-Čalogović, Dubravka
engleski
Diiodobis(1-methyl-1, 3-imidazolium-2-thiolato-S)mercury(II)
The reaction of 1-methyl-1, 3-imidazole-2-thione (meimtH) with mercury(II) iodide in methanol in a 2:1 molar ratio resulted in the formation of single crystals of the title compound, (HgI_2 (C_4 H_6 N_2 S)_2). The Hg atom is coordinated by two I (2.7809 (9) and 2.7999 (8) Å ; ; ) and two thione S atoms (2.520 (3) and 2.576 (3) Å ; ; ) with irregular tetrahedral coordination geometry. The NH groups of the imidazole ring take part in intra- and intermolecular hydrogen bonds with I atoms (N---I 3.596 (8) and 3.611 (9) Å ; ; , respectively) joining molecules into ininite chains parallel to the z axis.
crystal structure; diiodobis(1-methyl-1; 3-imidazolium-2-thiolato-S)mercury(II)
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Podaci o izdanju
56 (-)
2000.
801-803-x
objavljeno
0108-2701