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izvor podataka: crosbi

Stereoselective electrochemical reduction of 8-methylene-oleandomycin (CROSBI ID 160379)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Mandić, Zoran ; Ilijaš, Marina ; Turkalj, Gordana Stereoselective electrochemical reduction of 8-methylene-oleandomycin // Electrochemical and solid-state letters, 13 (2010), 4; E5-E6. doi: 10.1149/1.3294500

Podaci o odgovornosti

Mandić, Zoran ; Ilijaš, Marina ; Turkalj, Gordana

engleski

Stereoselective electrochemical reduction of 8-methylene-oleandomycin

The electrochemical reduction of 8-methylene-oleandomycin was investigated by cyclic voltammetry and preparative scale electrolysis. The electrochemical reduction in the exocyclic double bond predominantly gives one epimer with the estimated diastereomeric ratio of 5:1. (8S)-methyl-oleandomycin was identified as the main product of the reaction. Stereoselectivity of the electroreduction was explained by the “bottom-side” adsorption of the 8-methylene-oleandomycin through its conjugated double bond to the electrode surface.

8-methylene-oleandomycin ; stereoselectivity

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Podaci o izdanju

13 (4)

2010.

E5-E6

objavljeno

1099-0062

1944-8775

10.1149/1.3294500

Povezanost rada

Kemija, Kemijsko inženjerstvo

Poveznice
Indeksiranost