Stereoselective electrochemical reduction of 8-methylene-oleandomycin (CROSBI ID 160379)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Mandić, Zoran ; Ilijaš, Marina ; Turkalj, Gordana
engleski
Stereoselective electrochemical reduction of 8-methylene-oleandomycin
The electrochemical reduction of 8-methylene-oleandomycin was investigated by cyclic voltammetry and preparative scale electrolysis. The electrochemical reduction in the exocyclic double bond predominantly gives one epimer with the estimated diastereomeric ratio of 5:1. (8S)-methyl-oleandomycin was identified as the main product of the reaction. Stereoselectivity of the electroreduction was explained by the “bottom-side” adsorption of the 8-methylene-oleandomycin through its conjugated double bond to the electrode surface.
8-methylene-oleandomycin ; stereoselectivity
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Podaci o izdanju
13 (4)
2010.
E5-E6
objavljeno
1099-0062
1944-8775
10.1149/1.3294500
Povezanost rada
Kemija, Kemijsko inženjerstvo