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A three-component modular strategy to extend and link coordination complexes using halogen bonds to O-, S- and pi-acceptors

A modular strategy, involving the recognition and assembly of three molecular components, was used to decorate complexes of Ni(II) and Co(II) using halogen bonds of I···S and I···O type. In addition to this rational implementation of halogen bonding to extend coordination structures, the resulting materials also demonstrate the self-assembly via I···pi interactions as a means to form polymers based on coordination and halogen bonds.

Halogen-bonded metal complexes; three-component modular strategy; liquid assisted grinding; self-assembly

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