engleski

Crystal structures of modified PNA analogues and of cationic diimine Pd(II)-alkyl complex

Nature provides the best inspiration for development of new materials. Inorganic nucleic acid derivatives and structural mimics are receiving increased attention in recent years. We present four structures of Cu(II) complexes with amino acid substituted Di(2pyridyl) amine ligands which can serve as inorganic analogs of nucleic acids. Two of these structures have interesting intermolecular interactions and will be presented in the poster. In addition, we also present the structure of a monomer synthesized by reacting Pd(II) diimine complex with methyl methacrylate. This complex has been used to synthesize poly(alkene-block- alkene/carbon monoxide) copolymers. Late transition metal based systems have attracted attention recently, due to their lower oxophilicity and relatively high functionality tolerance. Catalytic synthesis of such copolymers is of immense interest as they may have new desirable properties.

PNA analogues ; synthesis of copolymers ; crystal structure

nije evidentirano