engleski

Electronic structure of 2, 5-dimethylazaferrocene

The electronic structure of 2, 5-dimethylazaferrocene has been studied by UV photoelectron spectroscopy(UPS) and high-level DFT methods. UPS data have been used to assign the previously reported spectrum of its radical-cation. We show that aza substitution enhances mixing/interaction between Fe 3d and ligand p-orbitals.

azaferrocenes ; photoelectron spectroscopy ; mMetal-ligand interactions

nije evidentirano