Theory of square-wave voltammetry of two-step electrode reaction using an inverse scan direction (CROSBI ID 172211)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Lovrić, Milivoj ; Komorsky-Lovrić, Šebojka
engleski
Theory of square-wave voltammetry of two-step electrode reaction using an inverse scan direction
A theory of square-wave voltammetry of two-step electrode reaction with kinetically controlled electron transfers is developed and a special case of thermodynamically unstable intermediate is analyzed. If the first reaction step is reversible and the second one is quasireversible, the response splits into two peaks if the scan direction is inverted. The separation of these peaks increases with frequency.
Square-wave voltammetry ; two-step electrode reaction ; theory of quasireversible EE mechanism
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Podaci o izdanju
2011
2011.
538341
6
objavljeno
2090-3529
10.4061/2011/538341
Povezanost rada
Kemija