Domino Diels-Alder reactions of 7-oxanorbornadiene-2, 3-dicarboximide: an elusive, highly reactive dienophile (CROSBI ID 172369)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Margetić, Davor ; Butler, Douglas N. ; Warrener, Ron N. ; Murata, Yasujiro
engleski
Domino Diels-Alder reactions of 7-oxanorbornadiene-2, 3-dicarboximide: an elusive, highly reactive dienophile
Flash vacuum pyrolysis (FVP) has been used to generate the novel 7-oxa-norbornadiene-2, 3-dicarboxylic imide that in situ gave an unprecedented cycloaddition reaction cascade with the imidofuran, a sideproduct of FVP. Stereoselectivity of cycloadditions was studied with the aid of density functional calculations, which fully support observed exo/endo-selectivity.
Diels-Alder reaction; furan; flash vacuum pyrolysis; DFT calculations; transition states
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