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Electrochemical regeneration of NADH on a glassy carbon electrode surface: The influence of electrolysis potential (CROSBI ID 173228)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Ali, Irshad ; Soomro, Bebul ; Omanović, Sasha Electrochemical regeneration of NADH on a glassy carbon electrode surface: The influence of electrolysis potential // Electrochemistry communications, 13 (2011), 6; 562-565. doi: 10.1016/j.elecom.2011.03.010

Podaci o odgovornosti

Ali, Irshad ; Soomro, Bebul ; Omanović, Sasha

engleski

Electrochemical regeneration of NADH on a glassy carbon electrode surface: The influence of electrolysis potential

The communication reports a surprising finding on the influence of electrode potential on the percentage of enzymatically active 1, 4-NADH produced by reduction of NAD+ in a batch electrochemical reactor, using a glassy carbon electrode. At the lowest cathodic electrolysis potential studied (−1.4 V vs. MSE), only 32% of 1, 4-NADH was found in the product mixture. However, at the highest cathodic electrolysis potential (−2.3 V vs. MSE), a surprisingly high amount (98%) of 1, 4-NADH was produced. The work demonstrates that, a batch electrochemical reactor employing a glassy carbon working electrode operated at high cathodic electrolysis potentials, represents a good candidate system for the regeneration of 1, 4-NADH in industrial bioreactors.

NADH; electrochemical regeneration; glassy carbon; electrode potential

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Podaci o izdanju

13 (6)

2011.

562-565

objavljeno

1388-2481

10.1016/j.elecom.2011.03.010

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Kemija

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