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izvor podataka: crosbi

Kinetic analysis of thermal decomposition of Ca(OH)_2 formed during hydration of commercial Portland cement by DSC (CROSBI ID 89333)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Zelić, Jelica ; Rušić, Davor ; Krstulović, Ruža Kinetic analysis of thermal decomposition of Ca(OH)_2 formed during hydration of commercial Portland cement by DSC // Journal of thermal analysis and calorimetry, 67 (2002), 3; 613-622

Podaci o odgovornosti

Zelić, Jelica ; Rušić, Davor ; Krstulović, Ruža

engleski

Kinetic analysis of thermal decomposition of Ca(OH)_2 formed during hydration of commercial Portland cement by DSC

In this paper, evaluation of kinetic parameters (the activation energy - E, the pre-exponential factor - A and the reaction order-n) with simultaneous determination of the possible reaction mechanism of thermal decomposition of calcium hydroxide (portlandite), Ca(OH)_2 formed during hydration of commercial Portland - slag cement, by means of differential scanning calorimetry (DSC) in non-isothermal conditions with a single heating-rate plot has been studied and discussed. The kinetic parameters and a mechanism function were calculated by fitting the experimental data to the integral, differential and rate equation methods.To determine the most probable mechanism, 30 forms of the solid-state mechanism functions, f(alpha(c)) have been tried. Having used the procedure developed and the appropriate program support, it has been established that the non-isothermal thermal decomposition of calcium hydroxide in the acceleratory period (0.004< α (c)<0.554)can be described by the rate equation: dα (c)/dT = A/β exp(-E/RT)f(α (c)), which is based on the concept of the mechanism reaction: f(α (c))=2(α (c))(1/2). The mechanism function as well as the values of the kinetic parameters are in good agreement with those given in literature.

Ca(OH)_2 portlandite ; DSC ; kinetic parameters ; non-isothermal kinetic ; reaction mechanism ; thermal decomposition.

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Podaci o izdanju

67 (3)

2002.

613-622

objavljeno

1388-6150

1588-2926

Povezanost rada

Kemijsko inženjerstvo

Indeksiranost