Synthesis and crystal structures of tetrakis(nitratomercurio)methane monohydrate and bis(sulphatomercurio)bis(aquamercurio)methane (CROSBI ID 78795)
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Podaci o odgovornosti
Grdenić, Drago ; Korpar-Čolig, Branka ; Matković-Čalogović, Dubravka
engleski
Synthesis and crystal structures of tetrakis(nitratomercurio)methane monohydrate and bis(sulphatomercurio)bis(aquamercurio)methane
The products of the reaction of Hofmann's base, [CHg4O(OH)(2)OH2](n), with cone. nitric and sulphuric acid are tetrakis(nitratomercurio)methane monohydrate, C(HgNO3)(4) . H2O and bis(sulphatomercurio)bis(aquamercurio)me C(HgSO4)(2)(HgOH2)(2). The structures were characterized by IR spectra and single crystal X-ray diffraction. In both structures the carbon atom is tetrahedrally surrounded by four mercury atoms.
mercury; tetramercurated methane; X-ray structure
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