Nalazite se na CroRIS probnoj okolini. Ovdje evidentirani podaci neće biti pohranjeni u Informacijskom sustavu znanosti RH. Ako je ovo greška, CroRIS produkcijskoj okolini moguće je pristupi putem poveznice www.croris.hr
izvor podataka: crosbi !

Novel hybrid inorganic-organic one-dimensional chain systems tailored with monocarboxylic acids (CROSBI ID 590345)

Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija

Djerdj, Igor ; Popović, Jasminka ; Stare, Jernej ; Ambrožić, Gabriela ; D. Škapin, Srečo ; Kozlevčar Bojan ; Pajić, Damir ; Jagličić, Zvonko ; Crnjak Orel, Zorica Novel hybrid inorganic-organic one-dimensional chain systems tailored with monocarboxylic acids // Book of Abstracts of the 27th European Crystallographic Meeting / Karl Wilhelm Törnroos (ur.). Bergen, 2012. str. 238-238

Podaci o odgovornosti

Djerdj, Igor ; Popović, Jasminka ; Stare, Jernej ; Ambrožić, Gabriela ; D. Škapin, Srečo ; Kozlevčar Bojan ; Pajić, Damir ; Jagličić, Zvonko ; Crnjak Orel, Zorica

engleski

Novel hybrid inorganic-organic one-dimensional chain systems tailored with monocarboxylic acids

Two novel nanosized hybrid inorganicorganic frameworks, VO(C14H9COO)2, and VO(C10H7COO)2 have been solvothermally synthesized and their structures elucidated using a combination of powder XRD and DFT geometry optimization [1]. They contain one-dimensional chain of corner-sharing tetrahedra in the case of VO(C10H7COO)2, and corner-sharing octahedra for VO(C14H9COO)2 oriented along orthorhombic/monoclinic c-axis, respectively. While VO(C14H9COO)2 exhibits bidentate bridging binding of organic moiety to the metal center, VO(C10H7COO)2 shows monodentate mode as evidenced from DFT and infrared spectroscopy. Both hybrids exhibit fiber-like morphology, consisting of smaller individual single crystals aligned in parallel to the growth direction along the c-axis. They are thermally stable up to 350°C having even more stable impurities containing vanadium in its highest oxidation state. The magnetic properties have been also investigated and indicate antiferromagnetic ordering along the chains characterized by rather low spin exchange parameters.

hybrid inorganic-organic materials; MOF; structure solution from PXRD; magnetic properties

nije evidentirano

nije evidentirano

nije evidentirano

nije evidentirano

nije evidentirano

nije evidentirano

Podaci o prilogu

238-238.

2012.

objavljeno

Podaci o matičnoj publikaciji

Book of Abstracts of the 27th European Crystallographic Meeting

Karl Wilhelm Törnroos

Bergen:

Podaci o skupu

27th European Crystallographic Meeting,

poster

06.08.2012-11.08.2012

Bergen, Norveška

Povezanost rada

Fizika, Kemija