Theory of square-wave voltammogram starting at the equilibrium potential (CROSBI ID 191069)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Jadreško, Dijana
engleski
Theory of square-wave voltammogram starting at the equilibrium potential
If both a reactant and product of an electrode reaction are present in the bulk of solution, the square-wave voltammogram can be recorded by starting at the equilibrium potential. If the reaction is reversible, the redox state of investigated substance can be estimated from the ratio of peak currents of the forward and backward components. The degree of reversibility of the reaction can be assessed from the current at the starting potential. Also, the dependence of the logarithm of forward component of irreversible response on the electrode potential can be used for the calculation of transfer coefficient.
square-wave voltammetry; equilibrium potential; theory; redox state; Tafel plot
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
Podaci o izdanju
693
2013.
56-59
objavljeno
1572-6657
10.1016/j.jelechem.2013.01.029