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Theory of square-wave voltammetry of dissolved redox couple (CROSBI ID 194662)

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Komorsky-Lovrić, Šebojka ; Lovrić, Milivoj Theory of square-wave voltammetry of dissolved redox couple // Advances in analytical chemistry, 3 (2013), 3A; 9-13. doi: 10.5923/s.aac.201307.02

Podaci o odgovornosti

Komorsky-Lovrić, Šebojka ; Lovrić, Milivoj

engleski

Theory of square-wave voltammetry of dissolved redox couple

A determination of the composition of dissolved mixture of reduced and oxidized forms of an electroactive compound by square-wave voltammetry is investigated theoretically. If electrode reaction is reversible, the sum of concentrations of these species can be measured by the standard addition method, while the ratio of their concentrations can be calculated from the ratio of the peak currents of the components of the response. If the transfer of electrons is kinetically controlled and the reduction and oxidation appear totally irreversible at the highest frequency, the concentrations of reactant and product may be measured separately

Square-wave voltammetry ; Theory ; Redox couple

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Podaci o izdanju

3 (3A)

2013.

9-13

objavljeno

2163-2839

2163-2847

10.5923/s.aac.201307.02

Povezanost rada

Kemija

Poveznice