HF-ESR studies of the compounds {;[Cu(bpy)3][Cu2(C2O4)3]•H2O};n and {;[Cu(bpy)3][Mn2(C2O4)3]•H2O};n (CROSBI ID 600671)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija
Podaci o odgovornosti
Žilić, Dijana ; Rakvin, Boris ; Jurić, Marijana ; Planinić, Pavica ; Pajić, Damir ; Zadro, Krešo ; Krupskaya, Yulia ; Kataev, Vladislav ; Büchner, Bernd
engleski
HF-ESR studies of the compounds {;[Cu(bpy)3][Cu2(C2O4)3]•H2O};n and {;[Cu(bpy)3][Mn2(C2O4)3]•H2O};n
The homometallic {;[Cu(bpy)3][Cu2(C2O4)3]•H2O};n (1) and the heterometallic {;[Cu(bpy)3][Mn2(C2O4)3]•H2O};n (2) compounds, where bpy = 2, 2'-bipyridine, consist of a three-dimensional (3D), polimeric anionic network [M2(C2O4)3]n2n– (where M = Cu2+ or Mn2+) with cations [Cu(bpy)3]2+ occupying the vacancies of the network. Frequency- and temperature-dependent high field electron spin resonance (HF-EPR) measurements on a polycrystalline sample of 1 and 2 are presented. Supported by X-band ESR on the polycrystalline of 1 and on the single crystal of 2, as well as, SQUID magnetization measurements, the magnetic properties of the compounds 1 and 2 are discussed.
HF-EPR; transition metal complexes
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Podaci o prilogu
DF 12.57-MA 16.57.
2013.
objavljeno
Podaci o matičnoj publikaciji
Verhandlungen der Deutschen Physikalischen Gesellschaft
Regensburg:
Podaci o skupu
DPG Spring Meeting of the Condensed Matter Section
poster
10.03.2013-15.03.2013
Regensburg, Njemačka