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Reactions Catalyzed by Halohydrin Dehalogenases (CROSBI ID 53645)

Prilog u knjizi | izvorni znanstveni rad

Majerić Elenkov, Maja ; Szymanski, Wiktor ; Janssen Dick B. Reactions Catalyzed by Halohydrin Dehalogenases // Science of Synthesis ; Biocatalysis in Organic Synthesis 2 / Faber, Kurt ; Fessner, Wolf-Dieter ; Turner, Nicholas (ur.). Stuttgart: Georg Thieme Verlag, 2014. str. 507-527

Podaci o odgovornosti

Majerić Elenkov, Maja ; Szymanski, Wiktor ; Janssen Dick B.

engleski

Reactions Catalyzed by Halohydrin Dehalogenases

In some bacteria, halohydrin dehalogenases catalyze the conversion of vicinal halo alco- hols, such as 1, 3-dichloropropane or 3-chloropropane-1, 2-diol, into epoxides, and thereby play a role in the biodegradation of halogenated organic compounds. In the reverse reaction, i.e. epoxide ring opening, various small anions can replace the halide, allowing the synthesis of β-substituted alcohols, including β-hydroxynitriles and β-azido alcohols. These remarkable catalytic properties have been modified by structure-based protein engineering, making the enzymes suitable for diverse applications.

Epoxides, Hydroxynitriles, Microorganisms, Alcohols, Cyanides

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Podaci o prilogu

507-527.

objavljeno

Podaci o knjizi

Science of Synthesis ; Biocatalysis in Organic Synthesis 2

Faber, Kurt ; Fessner, Wolf-Dieter ; Turner, Nicholas

Stuttgart: Georg Thieme Verlag

2014.

978-3-13-174161-5

Povezanost rada

Kemija