Separation of Cyclohexylisocyanate from the Crosslinked Copolymers of N-Acryl-dicyclohexylurea with Ethylene Glycol Dimethacrylate or Divinyl Benzene (CROSBI ID 93777)
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Podaci o odgovornosti
Erceg Kuzmić, Ana ; Vuković, Radivoje ; Bogdanić, Grozdana ; Fleš, Dragutin
engleski
Separation of Cyclohexylisocyanate from the Crosslinked Copolymers of N-Acryl-dicyclohexylurea with Ethylene Glycol Dimethacrylate or Divinyl Benzene
Copolymerization of N-acryl-N, N'-dicyclohexylurea with ethylene glycol dimethacrylate or divinyl benzene in the presence of dibenzoyl peroxide as initiator gave corresponding crosslinked copolymers. Both copolymers thermally decompose by two-step mechanism. In the first step separates cyclohexylisocyanate, thus forming the thermostable residue, which contains molecular imprints of cyclohexylisocyanates.
N-Acryl-N; N'-dicyclohexylurea; Poly(N-Acryl-N; N'-dicyclohexylurea)2-co-ethylene glycol dimethacrylate); Poly((N-Acryl-N; N'-dicyclohexylurea)2-co-divinyl benzene); Mechanism of copolymerization; Thermal properties; Molecularly imprinted crosslinked copolym
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Podaci o izdanju
40 (1)
2003.
81-85-x
objavljeno
1060-1325